Deselect the Automatically sync when this iPhone is connected setting
First, plug your iPhone into a laptop or desktop with its USB cable. iTunes will automatically open. Click the iPhone icon at the top left of the iTunes window. Click Summary. Deselect the Automatically sync when this iPhone is connected option
When you’ve deselected the Automatically sync when this iPhone is connected option, press the Apply button to confirm the new settings.
Configure the Device-Syncing Setting from Devices Preferences
You can also ensure iTunes doesn’t automatically open by adjusting an option on the Devices Preferences tab. Click Edit at the top left of the iTunes window. Select the Preferences option from the Edit menu. A General Preferences window opens that includes a Devices tab. Select the Devices tab on that window.
Click the selected Prevent iPods, iPhones, and iPads from syncing automatically check box shown below. Deselecting the option ensures that no devices sync with iTunes and that the software doesn’t open when you connect an iPhone with Windows laptops or desktops.
Press the OK button.
By configuring those settings, you have effectively switched auto syncing off. This ensures that iTunes no longer automatically opens to sync with devices when you connect the iPhone with Windows PC. However, that also switches off automatic backups for the mobile.
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